1. Volume & Dimensions
Total volume: 20 mL (usable slightly less, e.g., ~18 mL depending on cap/septum design)
Outer diameter: ~22.522.75 mm
Height: ~75 75.5 mm
Neck finish: ND20 (20 mm) crimp neck most common for headspace GC
2. Material
Glass type: Low-extractable borosilicate glass (USP Type I) high thermal resistance and chemical inertness for volatile analysis
Clear or amber glass available (amber for light-sensitive samples)
3. Bottom Style
Round bottom: Better for automated heating and rack handling.
Flat bottom: Better for manual heating/stability when placed on blocks.
Both are widely used; choice depends on autosampler type and heating method.
4. Closures & Septa
Cap type: Aluminum crimp cap (20 mm) with PTFE/silicone septa is typical.
Septa: PTFE/silicone or PTFE/butyl materials; low bleed variants are preferred for GC sensitivity.
Sealing: Crimp-top ensures tight sealing for pressurized headspace sampling.
5. Performance Features
High temperature and pressure tolerance: Designed to withstand internal pressures from heating during analysis without breakage.
Uniform wall thickness: Ensures even heating and reproducible headspace conditions.
Marking spot: Many vials include a writable area for sample ID.
6. Compliance & Use
Compatible with most headspace GC autosamplers (Agilent, Shimadzu, PerkinElmer, etc.).
Often supplied in pre-packaged sets with caps/septa.

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